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Alternative Solvent Degreasers

These degreasing and cleaning solvents are marketed as alternatives to halgonated solvents—especially chlorinated solvents. In some cases, these solvents require more time or stronger physical action for cleaning surfaces. All have lower rates of evaporation and drying than the chlorinated solvents they replace.

Safety Information
Most alternatives are safer than chlorinated solvents because their slow evaporation rates result in low worker exposure. Consider the following safety information when selecting an alternative chemical.

Exposure limit. Exposure limit estimates, based on
eight-hour exposure, given in the following table are
made by the Occupational Safety and Health Administration (OSHA), the American Congress of Governmental Industrial Hygienists (ACGIH), or the product manufacturer. OSHA establishes the legally enforceable standard. But, the ACGIH standard is generally recognized as the prudent industrial standard in the absence of an OSHA limit or when new information suggests an established OSHA limit is too lenient.

Vapor hazard ratio. The vapor hazard ratio is the likelihood that an exposure limit will be exceeded with normal use. It does not apply if the solvent will be sprayed or atomized. It is estimated by dividing the vapor pressure of a product, the tendency of a solvent to get into the air, by the exposure limit, its risk. The higher the number, the greater the chance the exposure limit will be exceeded due to solvent evaporation. This is a comparison of relative risks, this scale does not indicate if a chemical is unsafe.

Hazard rating. A hazard rating for health, flammability and reactivity is assigned to pure chemicals by the National Fire Protection Association (NFPA). A similar rating can be assigned to products by their manufacturer using the National Paint and Coatings Association (NPCA) Hazardous Materials Information Systems (HMIS) criteria. Because the HMIS is more subjective, the table on the following pages gives HMIS ratings only in the absence of NFPA ratings.

Alternative Solvent Degreasers
The cleaning claims in this reference list are made primarily by the manufacturer. Some claims are augmented by reports from the U.S. Environmental Protection Agency (EPA) and third parties. MnTAP maintains the following list of alternative solvent degreasers solely as a service to Minnesota companies. This is not a complete list of available suppliers and products, and does not represent an endorsement by MnTAP. MnTAP, by providing this list, does not represent that the products do or do not ensure compliance with environmental and safety laws in any specific application.

Table Key
a Vapor pressure measured at approximately 20º C.
b Vapor hazard ratio is calculated by dividing the vapor    pressure by 760 mm Hg, multiplying by one million to    estimate the equilibrium vapor concentration in parts per    million, and then dividing by the exposure limit in parts    per million.
c Estimated by the manufacturer, based on HMIS criteria.
d Practically non-flammable.

For More Information
MnTAP has a variety of technical assistance services available to help Minnesota businesses implement industry-tailored solutions that maximize resource efficiency, prevent pollution, increase energy efficiency, and reduce costs.Our information resources are available online. Or, call MnTAP at 612.624.1300 or 800.247.0015 from greater Minnesota for personal assistance.

 

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Supplier

Product/Residues Removed

Flash Point

Exposure Limit

Vapor Pressure (mmHg)a

Vapor
Hazard
Ratiob

Hazard
Rating

Ashland Chemicals
Columbus, OH
614/790-3333
800/582-0376

Ashland 142 Solvent, aliphatic hydrocarbon.
Removes: grease and oil.

142° F

100 ppm (ACGIH)

0.1

1.3

1:2:0

Brulin Corporation
Indianapolis, IN
317/923-3211
800/776-7149

SD 1291, propylene glycol ether and an ester. Removes: adhesive, grease and ink.

815MX, surfactants and amines. Removes: rosin solder flux.

160° F




>212° F

85 ppm (Brulin)


3 ppm (OSHA)

0.4



NA

6.2



NA

2:1:0



1:0:0

Chemsearch
St. Louis, MO
314/997-6311
800/325-8896

Voltz, petroleum-terpene blend. Removes: grease, ink, oil and tar.

142° F

300 ppm (OSHA)

0.7

3.1

1:2:0

Ecolink
Tucker, GA
800/886-8240
Aeroclean, dibasic ester. Removes: carbon, grease, oils and sealants.
Electron, terpene. Removes: carbon, grease, oil and resin.
Vortex, terpene. Removes: grease, oil, resin and tar.
216º F



124º F



147º F
not established


not established


not established
0.06



<1



0.3
NA



NA



NA

1:1:0c


1:2:0c



1:2:0c

Graymills Corporation
Chicago, IL
773/477-4100

Graymills Super Agitene 141, petroleum solvent.
Removes: grease, oil, light varnish and road dirt.

141° F

100 ppm (OSHA)

10

NA

1:2:0

Inland Technology
Tacoma, WA
800/552-3100

Breakthrough. Removes: grease and oil.
Citra-Safe. Removes: adhesive, flux, grease and oil.
Iso-Prep. Removes: adhesive, asphalt, grease, ink, oil and wax.
Skysol. Removes: grease and oil.
Teksol EP. Removes: flux, grease and oil.

150° F


132° F


104° F



152° F

112° F

not established

not established

not established


not established
not established

<2


<2


<10



<2

<2

NA


NA


NA



NA

NA

1:2:0


1:2:0


0:2:0



1:2:0

1:2:0

JNJ Industries
Franklin, MA
800/554-9994

GlobalTech Solvents, 6 ester-based solvents.
Removes: grease, oil, rosin flux and tar.

109 - 126° F

<100 ppm

1.5 - 12


1:2:0 - 2:2:0

Johnson Diversey Corporation/ DuBois Division
Cincinnati, OH
800/543-4906

DuSqueeze, terpene solvent and detergents.
Removes: dye, grease, ink, oil and uncured paint.

124° F

not established

17.5

NA

2:2:0

Kleen-Tec
Albert Lea, MN
507/373-5152
800/435-5336

Hi-T Degreasol 99R, petroleum solvent and detergents.
Removes: grease and oil.

141° F

100 ppm (OSHA)

0.1

1.3

1:2:0

Koal Industries
Elk Grove Village, IL
847/956-7920

Koal SS #471, aliphatic petroleum solvent.
Removes: grease and oil.

123° F

100 ppm

<1

13.2

1:2:0

Kyzen Corporation
Nashville, TN
615/831-0888 800/845-5524

Cybersolve C3400.
Removes: adhesive, buffing compound, flux, grease, pitch, tar and wax.
Ionox FCR, alcohol.
Removes: fingerprints and flux.
Metalox M6381, hydrocarbon solvent. Removes: grease, oil, pitch and tar.

142º F

 


212º F


142º F

not established




not established

not established

1.0





<0.6


1.5

NA





NA


NA

0:2:0

 


1:2:0


0:2:0

Orange Sol
Gilbert, AZ
800/877-7771

De-Solv-It, terpene solvent.
Removes: grease, oil, varnish, tar and wax.

205° F

not established

7.6

NA

NA

Petroferm
Fernandina Beach, FL
904/261-8286

Axarel 32. Removes: rosin flux.
Axarel 56. Removes: buffing and lapping compound, grease, oil and wax.
Axarel 6100 & 9100. Removes: grease, oil and wax. Axarels are blends of petroleum solvents and detergent.
Bioact AE-130, soy-based esters. Removes: asphalt and tar.
Bioact EC-7, terpene solvent and surfactants.
Removes: rosin flux.
Re-Entry, 2 terpene solvents. Removes: epoxies, grease, mold release, oil, paint, polishing compound, polyamides, polyesters and rosin flux.

205° F

205° F




142 - 205° F





285° F



117° F



151° F

not established
not established



1.5 ppm






not established


not established


100 ppm
(ACGIH)

<0.1

<0.1




<1.0






<2



1.6



0.28

NA

NA




87.7






NA



NA



3.7

2:1:1

2:1:0




2:2:0






1:1:0



1:2:0



1:2:0

Safety-Kleen
Plano, TX
972/265-2000
800/669-5740

Safety-Kleen Premium Solvent, petroleum solvent.
Removes: grease, light varnish and oil.

148° F

100 ppm

2

26.3

1:2:0

Solvent Kleene
Peabody, MA
978/531-2279

D-Greeze 500, petroleum solvent.
Removes: adhesive, buffing compound, grease, ink, low-melt wax and oil.

142° F

not established

0.7

NA

0:2:0

SOYSolve
Tiffin, OH
800/231-4274
6 soy-derived solvents. Removes: adhesive, asphalt, grease, ink, oil, paint and tar. 150 - 300º F not established 0.9 - 1.7 NA 1:1:1 - 1:2:2

Tarksol Environmental Products
Rochester, NY
585/663-3346

HTF-85B, terpene alcohol. Removes: flux, grease, wide variety of resins, and oil.
HTF-50, blend of terpenes and alcohol. Removes: epoxy, grease, paint, resins and urethane.

>203° F




>200° F

not established



not established

0.6




<0.14

NA




NA

1:1:0




1:1:0

Zep Manufacturing Company
Moundsview, MN
763/792-2050

ZEP 143, petroleum distillates.
Removes: grease and oil.
ZEP 170, petroleum distillates.
Removes: grease and oil.

143° F



170° F

100 ppm (Zep)


100 ppm (Zep)

<5



0.9

65.8



11.8

2:2:0c



2:2:0c

Halogenated Solvents for Comparison

Supplier

Product

Flash Point

Exposure Limit

Vapor Pressure (mmHg)a

Vapor Hazard Ratiob

Hazard Rating

Various

1,1,1-Trichloroethane

none

350 ppm (OSHA)

100

376

1:1:0

Production of this solvent was banned as of 1/1/96 due to its ozone-depleting potential.

Various n-Propyl bromide none 25 ppm (EPA proposed)
10 ppm (ACGIH)
134


134
7,050


17,600
2:1:0c


2:1:0c

Various

Trichloroethylene

90° Fd

50 ppm (OSHA)

60

1580

1:1:0

(5/06-27)
 
 
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